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Journal Articles

Time-dependence of differential G-values of OH radicals in water under Ne ion radiolysis

Taguchi, Mitsumasa; Kojima, Takuji

JAEA-Review 2005-001, TIARA Annual Report 2004, p.181 - 182, 2006/01

The yields of OH radicals in water containing phenol have been investigated for several ten MeV/n C ion and Ne ion having the same LET value, as a function of the residual ion energy at the specific depth in water. In this study, beside such energy dependence, the dependence of reaction time of OH radical yield was examined by changing the concentration of phenol as solute. The defferential G'-values of OH radicals, those G-values per kinetic energy of ions increase with specific energy of Ne ions. The G'-value just after irradiation(1.5ns) is relatively high but become lower with reaction time to be the value (2.7) obtained for $$^{60}$$Co $$gamma$$-rays. It suggests the diffusion behavior of OH radicals locally induced in water.

Journal Articles

Chain terminations in the decomposition reactions of chloroethylenes in air through the deposition of alkylperoxy radicals on the wall of an irradiation vessel

Hakoda, Teruyuki; Kojima, Takuji

Radiation Physics and Chemistry, 74(5), p.302 - 309, 2005/12

 Times Cited Count:0 Percentile:0.01(Chemistry, Physical)

no abstracts in English

Journal Articles

Application of electron beams for the treatment of VOC streams

Hirota, Koichi; Sakai, Hiroki*; Washio, Masakazu*; Kojima, Takuji

Industrial & Engineering Chemistry Research, 43(5), p.1185 - 1191, 2004/03

 Times Cited Count:46 Percentile:79.46(Engineering, Chemical)

Twenty volatile organic compounds (VOCs) were irradiated with electron beams in laboratory scale to obtain an electron-beam energy required for a 90% treatment. The experiments showed that the energy was related with the chemical structure and roughly estimated from rate constants for reactions with OH radicals. The cost analysis revealed that the unification of a self-shielding electron accelerator with a reactor could reduce the capital cost for an electron-beam system. Electron-beam technology is a promising method for the treatment of VOCs.

Journal Articles

ESR study on chemical crosslinking reaction mechanisms of polyethylene using a chemical agent, 4; Effect of sulfur- and phosphorous-type antioxidants

Yamazaki, Takanori*; Seguchi, Tadao

Journal of Polymer Science, Part A; Polymer Chemistry, 38(17), p.3092 - 3099, 2000/09

no abstracts in English

Journal Articles

Reaction mechanisms of silicon carbide fiber synthesis by heat treatment of polycarbosilane fibers cured by radiation, II; Free radical reaction

Sugimoto, Masaki; *; Okamura, K.*; Seguchi, Tadao

Journal of the American Ceramic Society, 78(7), p.1849 - 1852, 1995/00

 Times Cited Count:39 Percentile:84.73(Materials Science, Ceramics)

no abstracts in English

Journal Articles

Sterilization by radiation-induced water radical

Watanabe, Hiroshi

Kagaku Kogaku, 54(9), p.656 - 657, 1990/09

no abstracts in English

Journal Articles

Development of technique in radiation treatment of water

;

Radioisotopes, 34(10), p.570 - 579, 1985/00

no abstracts in English

Journal Articles

Relative reactivities of radioiodine released from U$$_{3}$$O$$_{8}$$ in oxygen and helium atmospheres toward propane

Nakashima, Mikio; Tachikawa, Enzo

Journal of Nuclear Science and Technology, 15(11), p.849 - 855, 1978/00

 Times Cited Count:3

no abstracts in English

Journal Articles

Carbon sources and formation mechanisms of organic iodides in nitric acid solutions

Saeki, Masakatsu; *; Tachikawa, Enzo

Int.J.Appl.Radiat.Isot., 25(9), p.407 - 414, 1974/09

 Times Cited Count:8

no abstracts in English

Journal Articles

An accelerating effect of halogenated methane on the radiation degradation of polytetrafluoroethylene

Hagiwara, Miyuki; *; *; *; *

Kobunshi Rombunshu, 31(5), p.336 - 340, 1974/05

no abstracts in English

Journal Articles

Mechanism of propagation, transfer and short-chain branching reaction in the free-radical porimerization of ethylene

*; Machi, Sueo; Hagiwara, Miyuki; *

Journal of Polymer Science, Part A-1, 5, p.3115 - 3128, 1967/00

no abstracts in English

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